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Elektronische Kommunikation auf molekularer Ebene : Aufbau und Untersuchung höherer Phenothiazin-Oligomere und -Polymere

Sailer, Markus

English Title: Electronic Communication on Molecular Level : Assembling and Investigation of Higher Phenothiazine Oligomers and Polymers

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Abstract

Aufbau und Untersuchung von elektronoisch aktiven Phenothiazinsystemen: Monodisperse Phenothiazinoligomere und Phenothiazin-Ferrocen-Hybridoligomere, Polymere und Copolymere und Donor-Akzeptorsysteme. Die Synthese der Zielverbindungen erfolgte über ein Baukastensystem aus unterschiedlich substituierten Phenothiazinderivaten mittels Suzuki-Kreuzkupplungsreaktion. Die Module wurden durch teils sequenzielle Reaktion (di)lithierter Vorstufen mit untzerschiedlichen Elektrophilen erzeugt.

Translation of abstract (English)

Assembling and investigation of electronic active phenothiazine systems: Monodisperse phenothiazine oligomers and phenothiazine-ferrocene hybrid oligomers, polymers and copolymers and donor-acceptor systems. Synthesis of the target molecules resulted via a building set of differently substituted phenothiazine derivatives by suzuki crosscoupling reaction. These modules were gernerated by partly sequential reaction of (di)lithiated precursors with various electrophiles.

Item Type: Dissertation
Supervisor: Müller, Prof. Dr. Thomas J. J.
Date of thesis defense: 3 November 2006
Date Deposited: 23 Nov 2006 11:24
Date: 2006
Faculties / Institutes: Fakultät für Chemie und Geowissenschaften > Institute of Organic Chemistry
Subjects: 540 Chemistry and allied sciences
Controlled Keywords: Phenothiazin, Phenothiazinderivate, Nanoelektronik, Molekularer Draht, Cyclopolymere, Polymere, Oligomere
Uncontrolled Keywords: monodisperse Oligomere , Lithium-Halogenaustausch , Yamamoto-Polymerisation , Suzuki-Polymerisation , sequenzielle Elektrophilzugabemonodisperse oligomers , Lithium halogen exchange , SEC , hybrid polymer , donor-acceptor systems
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