title: Reactive halogen species above salt lakes and salt pans creator: Holla, Robert subject: 500 subject: 500 Natural sciences and mathematics subject: 530 subject: 530 Physics subject: 550 subject: 550 Earth sciences description: Salt lakes can be found on all continents and saline soils cover 2.5% of the land surface of the earth (FAO, 2012). This thesis investigates the presence of reactive halogen species (RHS) above salt lakes and saline soils to evaluate their relevance for tropospheric chemistry of the planetary boundary layer. Ground-based MAX-DOAS and LP-DOAS measurements were conducted at salt lakes and two other sites with high halogen content. Prior to this work, RHS were found at three salt lakes with mixing ratios ranging from several pptv up to more than 100 pptv. On the basis of this work the data base on reactive halogen release from salt lakes was significantly expanded. Passive DOAS and active DOAS systems were used to examine the vertical as well as the horizontal distribution of BrO in the Dead Sea Valley. Vertical profiles of aerosols, BrO and NO2 were measured at two adjacent sites at the Dead Sea using MAX-DOAS. The first time vertical profiles of BrO and NO2 at the Dead Sea were determined and interpreted in terms of the special atmospheric dynamics in the Dead Sea Valley. The resulting ground values of BrO and NO2 at one measurement site were validated by LP-DOAS and show very good agreement. The field studies presented in this work showed, that the release of RHS in those regions is less widespread than previously assumed. date: 2013 type: Dissertation type: info:eu-repo/semantics/doctoralThesis type: NonPeerReviewed format: application/pdf identifier: https://archiv.ub.uni-heidelberg.de/volltextserverhttps://archiv.ub.uni-heidelberg.de/volltextserver/14636/1/Dissertation_Holla_Robert.pdf identifier: DOI:10.11588/heidok.00014636 identifier: urn:nbn:de:bsz:16-heidok-146365 identifier: Holla, Robert (2013) Reactive halogen species above salt lakes and salt pans. [Dissertation] relation: https://archiv.ub.uni-heidelberg.de/volltextserver/14636/ rights: info:eu-repo/semantics/openAccess rights: http://archiv.ub.uni-heidelberg.de/volltextserver/help/license_urhg.html language: eng