title: In-situ and ex-situ studies of barnacle proteinaceous cements settled at earlier time points using μ-Raman spectroscopy and synchrotron based X-ray microprobe fluorescence techniques creator: Mohamed, Tawheed Hashim Abdel-Razik subject: ddc-000 subject: 000 Generalities, Science subject: ddc-500 subject: 500 Natural sciences and mathematics subject: ddc-530 subject: 530 Physics subject: ddc-540 subject: 540 Chemistry and allied sciences subject: ddc-570 subject: 570 Life sciences subject: ddc-600 subject: 600 Technology (Applied sciences) description: Among the different biofouling species, barnacles resemble a specific threat as they are difficult to remove, able to damage fouling release coatings and increase the drag force of ships. Additionally, barnacles are a good model system for research on permanent underwater adhesion strategies. This study aims to understand and compare the spatial organization and the chemistry of the adhesive secreted by two different species (Balanus amphitrite and Balanus improvisus) of cyprid larvae and juvenile barnacles for settlement. Raman spectromicroscopy and synchrotron based X-ray microprobe fluorescence analysis have been applied for the in-situ and ex-situ investigation of juvenile barnacle cement chemistry. Confocal Raman spectromicroscopy revealed the chemical heterogeneity of the barnacle baseplate and allowed to distinguish three regions of various chemical compositions. The adhesive of cyprids was different from the one of larvae and analyzed in detail from the metamorphosis to the age of fourteen days. The results of these studies provided information on the chemical composition and morphological structure of both barnacle species at different life stages. date: 2014 type: Dissertation type: info:eu-repo/semantics/doctoralThesis type: NonPeerReviewed format: application/pdf identifier: https://archiv.ub.uni-heidelberg.de/volltextserverhttps://archiv.ub.uni-heidelberg.de/volltextserver/17207/1/Tawheed%20Thesis.pdf identifier: DOI:10.11588/heidok.00017207 identifier: urn:nbn:de:bsz:16-heidok-172073 identifier: Mohamed, Tawheed Hashim Abdel-Razik (2014) In-situ and ex-situ studies of barnacle proteinaceous cements settled at earlier time points using μ-Raman spectroscopy and synchrotron based X-ray microprobe fluorescence techniques. [Dissertation] relation: https://archiv.ub.uni-heidelberg.de/volltextserver/17207/ rights: info:eu-repo/semantics/openAccess rights: http://archiv.ub.uni-heidelberg.de/volltextserver/help/license_urhg.html language: eng