eprintid: 17207 rev_number: 18 eprint_status: archive userid: 1312 dir: disk0/00/01/72/07 datestamp: 2014-08-01 11:19:10 lastmod: 2014-08-14 08:07:30 status_changed: 2014-08-01 11:19:10 type: doctoralThesis metadata_visibility: show creators_name: Mohamed, Tawheed Hashim Abdel-Razik title: In-situ and ex-situ studies of barnacle proteinaceous cements settled at earlier time points using μ-Raman spectroscopy and synchrotron based X-ray microprobe fluorescence techniques subjects: ddc-000 subjects: ddc-500 subjects: ddc-530 subjects: ddc-540 subjects: ddc-570 subjects: ddc-600 divisions: i-120300 adv_faculty: af-12 abstract: Among the different biofouling species, barnacles resemble a specific threat as they are difficult to remove, able to damage fouling release coatings and increase the drag force of ships. Additionally, barnacles are a good model system for research on permanent underwater adhesion strategies. This study aims to understand and compare the spatial organization and the chemistry of the adhesive secreted by two different species (Balanus amphitrite and Balanus improvisus) of cyprid larvae and juvenile barnacles for settlement. Raman spectromicroscopy and synchrotron based X-ray microprobe fluorescence analysis have been applied for the in-situ and ex-situ investigation of juvenile barnacle cement chemistry. Confocal Raman spectromicroscopy revealed the chemical heterogeneity of the barnacle baseplate and allowed to distinguish three regions of various chemical compositions. The adhesive of cyprids was different from the one of larvae and analyzed in detail from the metamorphosis to the age of fourteen days. The results of these studies provided information on the chemical composition and morphological structure of both barnacle species at different life stages. date: 2014 id_scheme: DOI id_number: 10.11588/heidok.00017207 ppn_swb: 1658803493 own_urn: urn:nbn:de:bsz:16-heidok-172073 date_accepted: 2014-07-18 advisor: HASH(0x559e37e2a3d0) language: eng bibsort: MOHAMEDTAWINSITUANDE2014 full_text_status: public citation: Mohamed, Tawheed Hashim Abdel-Razik (2014) In-situ and ex-situ studies of barnacle proteinaceous cements settled at earlier time points using μ-Raman spectroscopy and synchrotron based X-ray microprobe fluorescence techniques. [Dissertation] document_url: https://archiv.ub.uni-heidelberg.de/volltextserver/17207/1/Tawheed%20Thesis.pdf