eprintid: 1841
rev_number: 8
eprint_status: archive
userid: 1
dir: disk0/00/00/18/41
datestamp: 2002-01-16 00:00:00
lastmod: 2014-04-03 11:27:43
status_changed: 2012-08-14 15:02:58
type: doctoralThesis
metadata_visibility: show
creators_name: Toimil Molares, Maria Eugenia
title: Fabrication and characterisation of copper nanowires electrochemically deposited in etched ion-track membranes
title_de: Herstellung und Charakterisierung von elektrochemisch in geätzten Ionenspurmembranen abgeschiedenen Kupfernanodrähten
ispublished: pub
subjects: ddc-530
divisions: i-130200
adv_faculty: af-13
keywords: Nanodrähte , Elektrochemische Abscheidung , geätzte Ionenspurmembran , Polykristallcopper , nanowire , electrochemical deposition , single-crystal , etched ion-track membrane
cterms_swd: Nanostruktur
cterms_swd: Einkristall
cterms_swd: Draht
cterms_swd:  Membran
cterms_swd: Kupferdraht
abstract_translated_text: Poly- and single-crystalline copper nanowires have been created by electrochemical deposition of copper in etched ion-track membranes. 30 µm thick polycarbonate foils were irradiated at the UNILAC (GSI, Darmstadt) with Au and Pb ions of kinetic energy 1-2 GeV with ?uences between 1 and 10^9 ions/cm^2. The latent tracks generated by the heavy ions were chemically etched providing membranes with cylindrical pores of diameter between 30 nm and µm. These membranes were used as templates for the growth of copper. Potentiostatic deposition of copper in membranes with large (several hundred nm) and small (several ten nm) diameter pores have been investigated using a two-electrode electrochemical cell. We present the results of a systematic study aimed at determination of the optimal deposition parameters (overvoltage, temperature, and electrolyte solution) required for single-crystalline growth. The morphology and crystallinity of the copper nanowires were studied by means of scanning electron microscopy, transmission electron microscopy and x-ray diffraction. Thus, from our results we can afirm that nanowires deposited at high temperatures (50 ?C) and overvoltages lower than 60 mV possess a single-crystalline structure. Polycrystalline wires were obtained from deposition at room temperature or at higher overvoltages. Typical defects of single- crystals as twins and slips were also observed. Two different techniques were tested to contact nanoneedles for electrical transport measurements.
abstract_translated_lang: eng
date: 2001
date_type: published
id_scheme: DOI
id_number: 10.11588/heidok.00001841
ppn_swb: 1643261886
own_urn: urn:nbn:de:bsz:16-opus-18411
date_accepted: 2001-12-18
advisor: HASH(0x561a62854370)
language: eng
bibsort: TOIMILMOLAFABRICATIO2001
full_text_status: public
citation:   Toimil Molares, Maria Eugenia  (2001) Fabrication and characterisation of copper nanowires electrochemically deposited in etched ion-track membranes.  [Dissertation]     
document_url: https://archiv.ub.uni-heidelberg.de/volltextserver/1841/1/DissertationToimil.pdf