TY - GEN AV - public Y1 - 2016/// TI - Optical and EUV spectroscopy of highly charged ions near the 4f?5s level crossing ID - heidok20759 N2 - In recent years, various highly charged ions (HCI) with optical transitions have been proposed for metrology and searches of a possible variation of the fine-structure constant ?. Optical transitions in HCI are uncommon due to the scaling of energy levels with atomic number Z^2 . At the 4f?5s level crossing, three configurations are nearly degenerate, and thus many optical transitions can exist. The complex many-electron couplings reduce the accuracy of current calculations. Moreover, experimental data to benchmark the predictions is lacking. Spectra in the optical and extreme-ultraviolet (EUV) range of several ion species near the 4f?5s level crossing were measured at the Heidelberg electron beam ion trap. A collisional-radiative model was employed for the interpretation of the EUV data, resulting in the first identification of the long sought-after 5s?5p transitions in Pm-like Re^14+ , Os^15+ , Ir^16+ , and Pt^17+. The characteristic line shapes of optical transitions in Ir17+ were studied, with the aim of identifying transitions with a high sensitivity to ?-variation. Previously suggested candidates could be excluded and new candidates were proposed. This data provides a stringent benchmark for state-of-the-art precision atomic theory. A1 - Bekker, Hendrik UR - https://archiv.ub.uni-heidelberg.de/volltextserver/20759/ ER -