%0 Generic
%A Müll, Damian
%C Heidelberg
%D 2023
%F heidok:32839
%R 10.11588/heidok.00032839
%T Photodetachment studies of negative ions at the Cryogenic Storage Ring
%U https://archiv.ub.uni-heidelberg.de/volltextserver/32839/
%X In the present work, experimental studies of the photodetachment process of the Si− and Al−4 systems are presented. The measurements were carried out at the Cryogenic Storage Ring (CSR) facility located at the Max Planck Institute for Nuclear Physics in Heidelberg. By storing Si− for up to 2000 s in the T < 10 K CSR environment, making use of the reduced blackbody radiation field inside the CSR, we were able to monitor the decay of long-lived 2D states as well as the weakly bound 2P states.  Employing a set of continuous wave and pulsed lasers, the lifetime for the 2P states were found to be τ = (22.5 ± 2.5)s. For the 2D states, a lower limit of τr > 5.7 h (within a confidence level of 90%) was measured. Furthermore, Multi-Configuration Dirac-Hartree-Fock (MCDHF) calculations were performed on the radiatiave lifetimes  of the respective states, which show very good agreement with the present measurement. The second part of the studies focuses on the study of spontaneous cooling of stored Al−4 ions at very long time scales. Here, we present measurements that allow us to monitor the cluster cooling rates for up to 30 min and we compare those results to previous measurements at a room temperature device. We find that the cooling time  scale is limited by the redistribution of vibrational energy inside the molecule, which we call slow exchange model, and in combination with recurrent fluorescence for energies above the first electronic excited state, they match the observed cooling rates.