eprintid: 35200
rev_number: 13
eprint_status: archive
userid: 8335
dir: disk0/00/03/52/00
datestamp: 2024-08-01 13:43:15
lastmod: 2024-08-16 09:08:13
status_changed: 2024-08-01 13:43:15
type: doctoralThesis
metadata_visibility: show
creators_name: Kotlear, Eugen A.
title: Synthese von Modulen für sterisch anspruchsvolle N/O-chelatisierende Liganden
subjects: ddc-540
divisions: i-120100
adv_faculty: af-12
cterms_swd: 1,2-Diketone
cterms_swd: alpha-Diketone
abstract: This doctoral thesis deals with derivatization of compound 1,2-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-ethanedione. For this purpose, different aromatic residues were used in combination with 1,2-diketone fragment. As starting compounds for the synthesis 1,3-dimethoxybenzene, 4-tert-butylphenol and 2-naphthol were used. The focus of the synthesis was to combine those to a new 1,2-
diketone and functionalize the aromatic residues with groups, that provide some steric effects. The emphasis was put on short synthesis, good yields and industrial scale up of all reactions. The second part focused on the cost-efficient synthesis of [1,1'-biphenyl]-3,3',5,5'-tetracarbaldehyde (tetraal) using commercially available stock chemicals with a scale up perspective. The third part examined the synthesis of imidazole using 1,2-diketones and tetraal according to Radziszewski synthesis.
date: 2024
id_scheme: DOI
id_number: 10.11588/heidok.00035200
ppn_swb: 1898866783
own_urn: urn:nbn:de:bsz:16-heidok-352001
date_accepted: 2024-07-19
advisor: HASH(0x561a62a45120)
language: ger
bibsort: KOTLEAREUGSYNTHESEVO20240729
full_text_status: public
place_of_pub: Heidelberg
citation:   Kotlear, Eugen A.  (2024) Synthese von Modulen für sterisch anspruchsvolle N/O-chelatisierende Liganden.  [Dissertation]     
document_url: https://archiv.ub.uni-heidelberg.de/volltextserver/35200/1/Dissertation.pdf