<> "The repository administrator has not yet configured an RDF license."^^ . <> . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy"^^ . "fine-structure transitions shift from the infrared to the optical range. The electronic states in nd and nf subshells cover a variety of different total angular momenta, potentially featuring higher-order multipole clock transitions. By utilising laser-induced ablation inside an electron beam ion trap (EBIT), restrictions on elements applicable as HCIs for optical spectroscopy have been\r\nlifted. Optical spectra of Pb21+ to Pb33+ and Bi9+ to Bi14+ were recorded with high resolution thanks to a newly developed algorithm to correct for thermal drifts. These were compared to dedicated atomic structure calculations. Information about the level structure of 4f3 to 5s24f13 in lead and 5d1\r\nto 5d6 in bismuth were inferred.\r\nThe presented level structure determinations are valuable as a benchmark\r\nfor atomic structure calculations and are an essential step towards\r\nvacuum-ultraviolet spectroscopy in the search for higher-order optical clock\r\ntransitions in the examined ions."^^ . "2024" . . . . . . . "Michael Karl"^^ . "Rosner"^^ . "Michael Karl Rosner"^^ . . . . . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy (PDF)"^^ . . . "phd_rosner_final.pdf"^^ . . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy (Other)"^^ . . . . . . "indexcodes.txt"^^ . . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy (Other)"^^ . . . . . . "lightbox.jpg"^^ . . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy (Other)"^^ . . . . . . "preview.jpg"^^ . . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy (Other)"^^ . . . . . . "medium.jpg"^^ . . . "Electronic energy level determination in the 4f-subshell in highly charged\r\nlead and the 5d-subshell in highly charged bismuth by atomic structure\r\ncalculation-assisted optical spectroscopy (Other)"^^ . . . . . . "small.jpg"^^ . . "HTML Summary of #35278 \n\nElectronic energy level determination in the 4f-subshell in highly charged \nlead and the 5d-subshell in highly charged bismuth by atomic structure \ncalculation-assisted optical spectroscopy\n\n" . "text/html" . . . "530 Physik"@de . "530 Physics"@en . .