eprintid: 6713 rev_number: 9 eprint_status: archive userid: 1 dir: disk0/00/00/67/13 datestamp: 2006-08-08 14:21:30 lastmod: 2014-08-20 15:55:26 status_changed: 2012-08-14 15:19:21 type: article metadata_visibility: show creators_name: Naegler, Tobias creators_name: Ciais, Philippe creators_name: Rodgers, Keith creators_name: Levin, Ingeborg title: Excess radiocarbon constraints on air-sea gas exchange and the uptake of CO2 by the oceans ispublished: pub subjects: 530 divisions: 130500 keywords: Gasaustausch , Radiokohlenstoffgas exchange , radiocarbon , carbon cycle cterms_swd: Kohlenstoffkreislauf note: L11802, doi:1029/2005GL025408 abstract: We re-assess the constraints that estimates of the global ocean excess radiocarbon inventory place on air-sea gas exchange. We found that the gas exchange scaling parameter aq cannot be constrained by the excess radiocarbon inventory alone. Non-negligible biases in different global wind speed datasets require a careful adaptation of aq to the wind field chosen. Furthermore, aq depends on the spatial and temporal resolution of the wind fields. We develop a new wind speed- and inventory-normalized gas exchange parameter aqN which takes into account these biases and which is easily adaptable to any new estimate of the ocean excess radiocarbon inventory. Our study yields an average estimate of aq of 0.32+/-0.05 for monthly mean winds, lower than the previous estimate (0.39) from Wwanninkhof (1992). We calculate a global annual average piston velocity for CO2 of (16.7+/-2.9) cm/hr and a gross CO2 flux between atmosphere and ocean of (73+/-10) PgC/yr, significantly lower than results from previous studies. abstract_translated_lang: eng class_scheme: pacs class_labels: 92.60.Cc, 92.20.Xy date: 2006 date_type: published id_scheme: DOI id_number: 10.11588/heidok.00006713 ppn_swb: 1644604906 own_urn: urn:nbn:de:bsz:16-opus-67139 language: eng bibsort: NAEGLERTOBEXCESSRADI2006 full_text_status: public publication: Geophysical Research Letters volume: 33 citation: Naegler, Tobias ; Ciais, Philippe ; Rodgers, Keith ; Levin, Ingeborg (2006) Excess radiocarbon constraints on air-sea gas exchange and the uptake of CO2 by the oceans. Geophysical Research Letters, 33. document_url: https://archiv.ub.uni-heidelberg.de/volltextserver/6713/1/NaeglerGRL2006.pdf