<> "The repository administrator has not yet configured an RDF license."^^ . <> . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches"^^ . "In this work, the challenging task of modelling Hydrogenase is subjected to three different approaches. The first strategy used here is bioorganometallic. A wide range of sulfur containing ferrocene-peptide derivatives were synthesized and fully characterized. As a second approach, organic self-assembled oligoquinoline were designed and synthesized. These two kind of structures were further used a scaffold for Hydrogenase mimics. In the third approach, a theoretical computational study of the ferrocene-peptide derivatives is led. In order to investigate a wider range of ferrocene-peptide as a molecular scaffold, a molecular force field was successfully implemented and validated for CHARMM. After the deprotection of the thiol group in the bioorganometallic approach, the free SH groups were coordinated with iron-carbonyl, so as to mimic the Fe-only Hydrogenase active site. The complexes thus obtained were comprehensively characterized and their electronic and electrochemical properties were extensively studied."^^ . "2006" . . . . . . . . "Xavier Richard de"^^ . "Hatten"^^ . "Xavier Richard de Hatten"^^ . . . . . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches (PDF)"^^ . . . "Dissertation_Xavier_deHatten.pdf"^^ . . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches (Other)"^^ . . . . . . "indexcodes.txt"^^ . . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches (Other)"^^ . . . . . . "lightbox.jpg"^^ . . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches (Other)"^^ . . . . . . "preview.jpg"^^ . . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches (Other)"^^ . . . . . . "medium.jpg"^^ . . . "Toward Hydrogenase mimicry : subjecting the problem to three different approaches (Other)"^^ . . . . . . "small.jpg"^^ . . "HTML Summary of #6988 \n\nToward Hydrogenase mimicry : subjecting the problem to three different approaches\n\n" . "text/html" . . . "570 Biowissenschaften, Biologie"@de . "570 Life sciences"@en . .