English Title: Electronic Communication on Molecular Level : Assembling and Investigation of Higher Phenothiazine Oligomers and Polymers
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Abstract
Aufbau und Untersuchung von elektronoisch aktiven Phenothiazinsystemen: Monodisperse Phenothiazinoligomere und Phenothiazin-Ferrocen-Hybridoligomere, Polymere und Copolymere und Donor-Akzeptorsysteme. Die Synthese der Zielverbindungen erfolgte über ein Baukastensystem aus unterschiedlich substituierten Phenothiazinderivaten mittels Suzuki-Kreuzkupplungsreaktion. Die Module wurden durch teils sequenzielle Reaktion (di)lithierter Vorstufen mit untzerschiedlichen Elektrophilen erzeugt.
Translation of abstract (English)
Assembling and investigation of electronic active phenothiazine systems: Monodisperse phenothiazine oligomers and phenothiazine-ferrocene hybrid oligomers, polymers and copolymers and donor-acceptor systems. Synthesis of the target molecules resulted via a building set of differently substituted phenothiazine derivatives by suzuki crosscoupling reaction. These modules were gernerated by partly sequential reaction of (di)lithiated precursors with various electrophiles.
| Document type: | Dissertation |
|---|---|
| Supervisor: | Müller, Prof. Dr. Thomas J. J. |
| Date of thesis defense: | 3 November 2006 |
| Date Deposited: | 23 Nov 2006 11:24 |
| Date: | 2006 |
| Faculties / Institutes: | Fakultät für Chemie und Geowissenschaften > Institute of Organic Chemistry |
| DDC-classification: | 540 Chemistry and allied sciences |
| Controlled Keywords: | Phenothiazin, Phenothiazinderivate, Nanoelektronik, Molekularer Draht, Cyclopolymere, Polymere, Oligomere |
| Uncontrolled Keywords: | monodisperse Oligomere , Lithium-Halogenaustausch , Yamamoto-Polymerisation , Suzuki-Polymerisation , sequenzielle Elektrophilzugabemonodisperse oligomers , Lithium halogen exchange , SEC , hybrid polymer , donor-acceptor systems |
